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Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors. 2024
Maria V Kashina, and
Konstantin V Luzyanin, and
Dmitry V Dar'in, and
Stanislav I Bezzubov, and
Mikhail A Kinzhalov
St. Petersburg University, 7-9 Universitetskaya Nab., St. Petersburg 199034, Russian Federation.
Metal-mediated self-assembly of isocyanides and methyl 4-aminopyrimidine-5-carboxylate leads to luminescent PdII and PtII complexes featuring C,N-cyclometalated acyclic diaminocarbene (ADC) ligands. The solid-state luminescent properties of these diaminocarbene derivatives are attributed to their triplet-state metal/metal-to-ligand charge-transfer (3MMLCT) nature, which is driven by attractive intermolecular M···M interactions further reinforced by the intramolecular π-π interactions even in the structure of the Pd compound, which is the first Pd-ADC phosphor reported.
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