Brittle and ductile yielding in soft materials. 2024

Krutarth M Kamani, and Simon A Rogers
Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Champaign, IL 61801.

Many soft materials yield under mechanical loading, but how this transition from solid-like behavior to liquid-like behavior occurs can vary significantly. Understanding the physics of yielding is of great interest for the behavior of biological, environmental, and industrial materials, including those used as inks in additive manufacturing and muds and soils. For some materials, the yielding transition is gradual, while others yield abruptly. We refer to these behaviors as being ductile and brittle. The key rheological signatures of brittle yielding include a stress overshoot in steady-shear-startup tests and a steep increase in the loss modulus during oscillatory amplitude sweeps. In this work, we show how this spectrum of yielding behaviors may be accounted for in a continuum model for yield stress materials by introducing a parameter we call the brittility factor. Physically, an increased brittility decreases the contribution of recoverable deformation to plastic deformation, which impacts the rate at which yielding occurs. The model predictions are successfully compared to results of different rheological protocols from a number of real yield stress fluids with different microstructures, indicating the general applicability of the phenomenon of brittility. Our study shows that the brittility of soft materials plays a critical role in determining the rate of the yielding transition and provides a simple tool for understanding its effects under various loading conditions.

UI MeSH Term Description Entries

Related Publications

Krutarth M Kamani, and Simon A Rogers
October 2020, Physical review letters,
Krutarth M Kamani, and Simon A Rogers
June 2018, Proceedings of the National Academy of Sciences of the United States of America,
Krutarth M Kamani, and Simon A Rogers
October 2010, Physical review letters,
Krutarth M Kamani, and Simon A Rogers
September 2014, The Journal of chemical physics,
Krutarth M Kamani, and Simon A Rogers
August 2020, Advances in colloid and interface science,
Krutarth M Kamani, and Simon A Rogers
January 2003, Pharmaceutical development and technology,
Krutarth M Kamani, and Simon A Rogers
December 2017, Soft matter,
Krutarth M Kamani, and Simon A Rogers
November 2010, Physical review letters,
Krutarth M Kamani, and Simon A Rogers
June 2012, Recent patents on nanotechnology,
Krutarth M Kamani, and Simon A Rogers
December 2022, Science (New York, N.Y.),
Copied contents to your clipboard!