Some properties of solubilized human rhodopsin. 1985

F Crescitelli

This investigation involved an examination of some properties of solubilized human rhodopsin. In confirmation of previous work, the spectral maximum was found to be at 493 nm at temperatures 5-10 degrees C below 37.5 degrees C. An increase in temperature to 37.5 degrees C produced only a minor shift of 2-4 nm toward the blue. The opsin displayed the classic and typical stereospecificity of vertebrate visual pigments, regenerating a pigment at 493 nm with 11-cis retinal and an isopigment at 483 nm with 9-cis retinal. No regeneration occurred with either all-trans or 13-cis retinal. The chromophoric photosensitivity of human rhodopsin and of its 11-cis regenerated pigment was found to be the same at 13.2 X 10(-17) cm2; that of the isopigment, at 4.5 X 10(-17) cm2. The long-lived photoproduct of human rhodopsin at 475 nm (metarhodopsin-III) was found to be especially interesting because of its protracted growth following a brief (20 sec) light exposure of the pigment and because of its long decay time even at 27 degrees C and higher. This property (growth and decay of metarhodopsin-III) was studied at temperatures ranging from 1.9 to 37.5 degrees C. Though NH2OH (4.6 X 10(-3) M) was found to speed the decay of metarhodopsin-III, it did not prevent its presence during decay for minutes after the 20-sec bleach. It is clear that the human metarhodopsin-III is indeed a long-lived intermediate of bleaching and evidence from the literature, which is cited, suggests that this product persists for significant periods of time in the retinas of mammals, including that of man. This fact suggests the possible physiological role of metarhodopsin-III in some aspects of vertebrate vision.

UI MeSH Term Description Entries
D008027 Light That portion of the electromagnetic spectrum in the visible, ultraviolet, and infrared range. Light, Visible,Photoradiation,Radiation, Visible,Visible Radiation,Photoradiations,Radiations, Visible,Visible Light,Visible Radiations
D010777 Photochemistry A branch of physical chemistry which studies chemical reactions, isomerization and physical behavior that may occur under the influence of visible and/or ultraviolet light. Photochemistries
D006358 Hot Temperature Presence of warmth or heat or a temperature notably higher than an accustomed norm. Heat,Hot Temperatures,Temperature, Hot,Temperatures, Hot
D006801 Humans Members of the species Homo sapiens. Homo sapiens,Man (Taxonomy),Human,Man, Modern,Modern Man
D012168 Retinal Pigments Photosensitive protein complexes of varied light absorption properties which are expressed in the PHOTORECEPTOR CELLS. They are OPSINS conjugated with VITAMIN A-based chromophores. Chromophores capture photons of light, leading to the activation of opsins and a biochemical cascade that ultimately excites the photoreceptor cells. Retinal Photoreceptor Pigment,Retinal Pigment,Visual Pigment,Visual Pigments,Retinal Photoreceptor Pigments,Photoreceptor Pigment, Retinal,Photoreceptor Pigments, Retinal,Pigment, Retinal,Pigment, Retinal Photoreceptor,Pigment, Visual,Pigments, Retinal,Pigments, Retinal Photoreceptor,Pigments, Visual
D012243 Rhodopsin A purplish-red, light-sensitive pigment found in RETINAL ROD CELLS of most vertebrates. It is a complex consisting of a molecule of ROD OPSIN and a molecule of 11-cis retinal (RETINALDEHYDE). Rhodopsin exhibits peak absorption wavelength at about 500 nm. Visual Purple
D013057 Spectrum Analysis The measurement of the amplitude of the components of a complex waveform throughout the frequency range of the waveform. (McGraw-Hill Dictionary of Scientific and Technical Terms, 6th ed) Spectroscopy,Analysis, Spectrum,Spectrometry
D013237 Stereoisomerism The phenomenon whereby compounds whose molecules have the same number and kind of atoms and the same atomic arrangement, but differ in their spatial relationships. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed) Molecular Stereochemistry,Stereoisomers,Stereochemistry, Molecular,Stereoisomer
Copied contents to your clipboard!