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Isolation, characterization and structure of a new allenic polyine antibiotic produced by fungus LL-07F275. 1995
G Schlingmann, and
L Milne, and
C J Pearce, and
D B Borders, and
M Greenstein, and
W M Maiese, and
G T Carter
American Cyanamid Company, Medical Research Division, Lederle Laboratories, Pearl River, N.Y. USA 10965, USA.
Antibiotic 07F275 (1), produced by submerged fermentations of fungal culture LL-07F275, was isolated and characterized despite its inherent instability. Its UV spectrum was identical with that of nemotin, a member of the allenic polyacetylene family, but a molecular weight of 218 daltons indicated a new compound. Structure 1 was determined on the basis of spectroscopic evidence, particularly NMR. Since 1 is a thirteen carbon-containing allenic diyne, it is closely related to mycomycin.
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