[Alpha-hydroxy-acid dehydrogenase activity in Trypanosoma cruzi]. 1976

N M Gerez de Burgos, and C Burgos, and A Blanco, and I Paulone, and E L Segura

Crude extracts of culture forms of epimastigotes, Tulahuén strain, showed activity to catalyze the reaction alpha-ketocid in equilibrium alpha-hydroxyacid linked to nicotinamide adenine dinucleotide (NAD). The enzyme utilizes the following substrates: alpha-ketobutyrate, alpha-ketoisovalerate, alpha-keto-beta-methylvalerate, alpha-ketocaproate, alpha-ketoisocaproate, alpha-ketoglutarate and pyruvate. Kinetics for the three last substrates were of the Michaelian type. For the other ketocids, curves of activity against substrate concentration exhibited a bimodal character. Km and V values for alpha-ketoisocaproate were strikingly higher than those for the other substrates. Electrophoretic separation of extracts on polyacrylamide gel and specific staining showed a single zone of enzymatic activity with similar mobility for all the alpha-OH-acids tested. This finding would indicate that the same protein is responsible for the reaction. The observations presented demonstrate that culture forms of Trypanosoma cruzi possess the ability to interconvert pyruvate in equilibrium lactate and to regenerate NAD in anaerobiosis. Although the physiological significance of the reaction with alpha-ketoacids other than pyruvate is not known, similarity of substrate of substrate spectrum between alpha-OH-acid dehydrogenase from Trypanosoma cruzi and lactate dehydrogenase ioenzyme X from mammalian and avian spermatozoa is interesting. Perhaps activity of flagella requires analogous metabolic pathways.

UI MeSH Term Description Entries
D006880 Hydroxy Acids Organic compounds containing both the hydroxyl and carboxyl radicals. Hydroxy Acid,Acid, Hydroxy,Acids, Hydroxy
D000429 Alcohol Oxidoreductases A subclass of enzymes which includes all dehydrogenases acting on primary and secondary alcohols as well as hemiacetals. They are further classified according to the acceptor which can be NAD+ or NADP+ (subclass 1.1.1), cytochrome (1.1.2), oxygen (1.1.3), quinone (1.1.5), or another acceptor (1.1.99). Carbonyl Reductase,Ketone Reductase,Carbonyl Reductases,Ketone Reductases,Oxidoreductases, Alcohol,Reductase, Carbonyl,Reductase, Ketone,Reductases, Carbonyl,Reductases, Ketone
D000818 Animals Unicellular or multicellular, heterotrophic organisms, that have sensation and the power of voluntary movement. Under the older five kingdom paradigm, Animalia was one of the kingdoms. Under the modern three domain model, Animalia represents one of the many groups in the domain EUKARYOTA. Animal,Metazoa,Animalia
D014349 Trypanosoma cruzi The agent of South American trypanosomiasis or CHAGAS DISEASE. Its vertebrate hosts are man and various domestic and wild animals. Insects of several species are vectors. Trypanosoma cruzus,cruzi, Trypanosoma

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