BIOMAT Database Logo BIOMAT Database Logo

2,3,4-Tri-O-acetyl-1,6-anhydro-beta-D-mannopyranose, an artifact produced during carbohydrate analysis. A total synthesis of 2,3,5-tri-O-acetyl-1,6-anhydro-beta-D-mannofuranose. 1993

S Manna, and B H McAnalley, and H L Ammon
Synthetic Organic Division, Carrington Laboratories, Inc., Dallas, TX 75356-9500.

This study confirms that 2,3,4-tri-O-acetyl-1,6-anhydro-beta-D-mannopyranose is an artifact produced during carbohydrate analysis. A new synthesis of 2,3,5-tri-O-acetyl-1,6-anhydro-beta-D-mannofuranose is also described, and a novel dimer, 1,6':6,1'-dianhydro-2,3:2',3'-di-O-isopropylidene-5,5'-di-O-(1-methox yethyl)-di - alpha-D-mannofuranose, has been isolated. The structure of the dimer is confirmed by X-ray analysis of a derivative, 1,6':6,1'-dianhydro-2,3:2',3'-di-O-isopropylidene-di-alpha-D-mannofur anose.

UI MeSH Term Description Entries
D007202 Indicators and Reagents Substances used for the detection, identification, analysis, etc. of chemical, biological, or pathologic processes or conditions. Indicators are substances that change in physical appearance, e.g., color, at or approaching the endpoint of a chemical titration, e.g., on the passage between acidity and alkalinity. Reagents are substances used for the detection or determination of another substance by chemical or microscopical means, especially analysis. Types of reagents are precipitants, solvents, oxidizers, reducers, fluxes, and colorimetric reagents. (From Grant & Hackh's Chemical Dictionary, 5th ed, p301, p499) Indicator,Reagent,Reagents,Indicators,Reagents and Indicators
D008358 Mannose A hexose or fermentable monosaccharide and isomer of glucose from manna, the ash Fraxinus ornus and related plants. (From Grant & Hackh's Chemical Dictionary, 5th ed & Random House Unabridged Dictionary, 2d ed) D-Mannose,Mannopyranose,Mannopyranoside,D Mannose
D008958 Models, Molecular Models used experimentally or theoretically to study molecular shape, electronic properties, or interactions; includes analogous molecules, computer-generated graphics, and mechanical structures. Molecular Models,Model, Molecular,Molecular Model
D008969 Molecular Sequence Data Descriptions of specific amino acid, carbohydrate, or nucleotide sequences which have appeared in the published literature and/or are deposited in and maintained by databanks such as GENBANK, European Molecular Biology Laboratory (EMBL), National Biomedical Research Foundation (NBRF), or other sequence repositories. Sequence Data, Molecular,Molecular Sequencing Data,Data, Molecular Sequence,Data, Molecular Sequencing,Sequencing Data, Molecular
D009682 Magnetic Resonance Spectroscopy Spectroscopic method of measuring the magnetic moment of elementary particles such as atomic nuclei, protons or electrons. It is employed in clinical applications such as NMR Tomography (MAGNETIC RESONANCE IMAGING). In Vivo NMR Spectroscopy,MR Spectroscopy,Magnetic Resonance,NMR Spectroscopy,NMR Spectroscopy, In Vivo,Nuclear Magnetic Resonance,Spectroscopy, Magnetic Resonance,Spectroscopy, NMR,Spectroscopy, Nuclear Magnetic Resonance,Magnetic Resonance Spectroscopies,Magnetic Resonance, Nuclear,NMR Spectroscopies,Resonance Spectroscopy, Magnetic,Resonance, Magnetic,Resonance, Nuclear Magnetic,Spectroscopies, NMR,Spectroscopy, MR
D002236 Carbohydrate Conformation The characteristic 3-dimensional shape of a carbohydrate. Carbohydrate Linkage,Carbohydrate Conformations,Carbohydrate Linkages,Conformation, Carbohydrate,Conformations, Carbohydrate,Linkage, Carbohydrate,Linkages, Carbohydrate
D002240 Carbohydrate Sequence The sequence of carbohydrates within POLYSACCHARIDES; GLYCOPROTEINS; and GLYCOLIPIDS. Carbohydrate Sequences,Sequence, Carbohydrate,Sequences, Carbohydrate
D016477 Artifacts Any visible result of a procedure which is caused by the procedure itself and not by the entity being analyzed. Common examples include histological structures introduced by tissue processing, radiographic images of structures that are not naturally present in living tissue, and products of chemical reactions that occur during analysis. Artefacts,Artefact,Artifact

Related Publications

S Manna, and B H McAnalley, and H L Ammon
High-pressure dielectric studies on 1,6-anhydro-β-D-mannopyranose (plastic crystal) and 2,3,4-tri-O-acetyl-1,6-anhydro-β-D-glucopyranose (canonical glass).
May 2018, The Journal of chemical physics,
S Manna, and B H McAnalley, and H L Ammon
Copolymerization of 1,6-anhydro-2,3,4-tri-O-(p-methylbenzyl)-beta-D-glucopyranose and 1,6-anhydro-2,3,4-tri-O-benzyl-beta-D-galactopyranose. Possible application to the synthesis of stereoregular heteropolysaccharides and oligosaccharides.
January 1973, Macromolecules,
S Manna, and B H McAnalley, and H L Ammon
Selective synthesis of 1,6-anhydro-β-d-mannopyranose and -mannofuranose using microwave-assisted heating.
September 2011, Carbohydrate research,
S Manna, and B H McAnalley, and H L Ammon
Synthesis of anomers of 6-O-tosyl-1,3,4-tri-O-acetyl-N-acetyl-D-glucosamine and 1,6-anhydro-N-acetyl-beta-D-glucosamin.
November 1962, Chemical & pharmaceutical bulletin,
S Manna, and B H McAnalley, and H L Ammon
Synthesis of 1,2-di-s-acetyl-1,2-dithio-3,4,6-tri-O-acetyl-beta-D-mannopyranose.
December 1965, Chemical & pharmaceutical bulletin,
S Manna, and B H McAnalley, and H L Ammon
An expedient synthesis of benzyl 2,3,4-tri-O-benzyl-beta-D-glucopyranoside and benzyl 2,3,4-tri-O-benzyl-beta-D-mannopyranoside.
May 2005, Carbohydrate research,
S Manna, and B H McAnalley, and H L Ammon
Steric control in the polymerization of 1,2-anhydro-3,4,6-tri-O-benzyl-beta-D-mannopyranose.
January 1985, Carbohydrate research,
S Manna, and B H McAnalley, and H L Ammon
[1,6-anhydro-N-acetyl-beta-D-glucosamines in synthesis of oligosaccharides. I. Synthesis of 3-acetate and 3-benzoate of 1,6-anhydro-N-acetyl-beta-D-glucosamine through a 4-O-trityl derivative].
June 2000, Bioorganicheskaia khimiia,
S Manna, and B H McAnalley, and H L Ammon
Syntheses and reactions of 5-O-acetyl-1,2-anhydro-3-O-benzyl-alpha-D-ribofuranose and beta-D-lyxofuranose, 5-O-acetyl-1,2-anhydro-3,6-di-O-benzyl- and 1,2-anhydro-5,6-di-O-benzoyl-3-O-benzyl-beta-D-mannofuranose, and 6-O-acetyl-1,2-anhydro-3,4-di-O-benzyl-alpha-D-glucopyranose and -beta-D-talopyranose.
January 2001, Carbohydrate research,
S Manna, and B H McAnalley, and H L Ammon
Synthesis of 1,2,3-tri-O-beta-lactosyl-D-threitol and 1-O-benzyl-2,3,4-tri-O-beta-lactosyl-D-threitol.
December 1997, Carbohydrate research,
Copied contents to your clipboard!