[The Influence of the Permeability of the Cell Membrane on TMPD Oxydase Activity (author's transl)]. 1977

R Holländer

26 bacterial strains representing a variety of both Gram-negative and Gram-postive groups were investigated for their N,N,N',N'-Tetramethyl-1, 4-phenylendiamin (TMPD) oxidase activities and cytochrome contents. The oxidase activites of colonies were examined by dropping the reagent on agar surface colonies. Intact and sonicated cells were tested by recording the oxidation of the TMPD reagent at 546 nm after addition to the cell suspensions. Cytochromes were determined by recording the difference spectra (KBH4-reduced minus H2O2-oxidized) between 400nm and 630 nm. After sonication of intact cells of the "oxidase negative" Enterobacteriaceae except the Proteus strains, the Flavobacterium strains, Streptococcus faecalis, Xanthomonas phaseoli, and the Acinetobacter strains investigated oxidase activities were observed and the oxidase activities of the "oxidase positive" Bacillus and Micrococcus strains and Haemophilus influenzae were increases. These observations show that negative oxidase reactions exhibited by bacterial colonies may not only be due to the lack of the oxidizing enzyme system itself but also to impermeability of the cell membrane for the TMPD reagent. The TMPD oxidase activity could not be correlated to the cytochrome contents of the cells.

UI MeSH Term Description Entries
D010088 Oxidoreductases The class of all enzymes catalyzing oxidoreduction reactions. The substrate that is oxidized is regarded as a hydrogen donor. The systematic name is based on donor:acceptor oxidoreductase. The recommended name will be dehydrogenase, wherever this is possible; as an alternative, reductase can be used. Oxidase is only used in cases where O2 is the acceptor. (Enzyme Nomenclature, 1992, p9) Dehydrogenases,Oxidases,Oxidoreductase,Reductases,Dehydrogenase,Oxidase,Reductase
D002463 Cell Membrane Permeability A quality of cell membranes which permits the passage of solvents and solutes into and out of cells. Permeability, Cell Membrane
D003580 Cytochromes Hemeproteins whose characteristic mode of action involves transfer of reducing equivalents which are associated with a reversible change in oxidation state of the prosthetic group. Formally, this redox change involves a single-electron, reversible equilibrium between the Fe(II) and Fe(III) states of the central iron atom (From Enzyme Nomenclature, 1992, p539). The various cytochrome subclasses are organized by the type of HEME and by the wavelength range of their reduced alpha-absorption bands. Cytochrome
D001419 Bacteria One of the three domains of life (the others being Eukarya and ARCHAEA), also called Eubacteria. They are unicellular prokaryotic microorganisms which generally possess rigid cell walls, multiply by cell division, and exhibit three principal forms: round or coccal, rodlike or bacillary, and spiral or spirochetal. Bacteria can be classified by their response to OXYGEN: aerobic, anaerobic, or facultatively anaerobic; by the mode by which they obtain their energy: chemotrophy (via chemical reaction) or PHOTOTROPHY (via light reaction); for chemotrophs by their source of chemical energy: CHEMOLITHOTROPHY (from inorganic compounds) or chemoorganotrophy (from organic compounds); and by their source for CARBON; NITROGEN; etc.; HETEROTROPHY (from organic sources) or AUTOTROPHY (from CARBON DIOXIDE). They can also be classified by whether or not they stain (based on the structure of their CELL WALLS) with CRYSTAL VIOLET dye: gram-negative or gram-positive. Eubacteria
D013772 Tetramethylphenylenediamine Used in the form of the hydrochloride as a reagent in ANALYTICAL CHEMISTRY TECHNIQUES. Wurster Blue,Wurster's Blue,Wurster's Reagent,Blue, Wurster,Blue, Wurster's,Reagent, Wurster's,Wurster Reagent,Wursters Blue,Wursters Reagent

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