Gas-solid chromatographic confirmation of vinyl chloride levels in oils and vinegars by using electrolytic conductivity detection. 1977

B D Page, and R O'Grady

A gas-solid chromatographic headspace method has been developed for the quantitative confirmation of vinyl chloride (VC) in oils, and vinegars. The method, based on the electrolytic conductivity detector, permits quantitative confirmation of VC residues as low 0.05 and 0.02 ppm for oil and vinegar, respectively. A number of samples were analyzed by using a previously reported flame ionization method and the proposed technique. The results by using the latter technique averaged 5% lower.

UI MeSH Term Description Entries
D009821 Oils Unctuous combustible substances that are liquid or easily liquefiable on warming, and are soluble in ether but insoluble in water. Such substances, depending on their origin, are classified as animal, mineral, or vegetable oils. Depending on their behavior on heating, they are volatile or fixed. (Dorland, 28th ed)
D002849 Chromatography, Gas Fractionation of a vaporized sample as a consequence of partition between a mobile gaseous phase and a stationary phase held in a column. Two types are gas-solid chromatography, where the fixed phase is a solid, and gas-liquid, in which the stationary phase is a nonvolatile liquid supported on an inert solid matrix. Chromatography, Gas-Liquid,Gas Chromatography,Chromatographies, Gas,Chromatographies, Gas-Liquid,Chromatography, Gas Liquid,Gas Chromatographies,Gas-Liquid Chromatographies,Gas-Liquid Chromatography
D004553 Electric Conductivity The ability of a substrate to allow the passage of ELECTRONS. Electrical Conductivity,Conductivity, Electric,Conductivity, Electrical
D005504 Food Analysis Measurement and evaluation of the components of substances to be taken as FOOD. Analysis, Food,Analyses, Food,Food Analyses
D000085 Acetates Derivatives of ACETIC ACID. Included under this heading are a broad variety of acid forms, salts, esters, and amides that contain the carboxymethane structure. Acetate,Acetic Acid Esters,Acetic Acids,Acids, Acetic,Esters, Acetic Acid
D014752 Vinyl Chloride A gas that has been used as an aerosol propellant and is the starting material for polyvinyl resins. Toxicity studies have shown various adverse effects, particularly the occurrence of liver neoplasms. Chloroethylene,Chloride, Vinyl
D014753 Vinyl Compounds Compounds containing the vinyl (-C Compounds, Vinyl

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