[Contribution to the standardization of results in paper and thin-layer chromatography (author's transl)]. 1977

J Churácek, and H Pechová, and J Chovanec

Chromatographic indexes that facilitate a better reproducibility of paper chromatographic results have been proposed, using the homologous series of coloured derivatives of secondary amines as standard substances. When using dimethylformamide as the stationary phase the value of the indexes proved to be independent of the concentration of the impregnating solution of the stationary phase, of the temperature changes during the chromatographic process, of the ways of impregnation and of the skills of workers. It depends only on the type of the stationary phase and on the composition of the mobile phase. The obtained indexes can contribute to a better reproducibility of RF values and to an easier and more objective identification of substances.

UI MeSH Term Description Entries
D009579 Nitrobenzoates Benzoic acid or benzoic acid esters substituted with one or more nitro groups. Nitrobenzoic Acids,Acids, Nitrobenzoic
D011786 Quality Control A system for verifying and maintaining a desired level of quality in a product or process by careful planning, use of proper equipment, continued inspection, and corrective action as required. (Random House Unabridged Dictionary, 2d ed) Control, Quality,Controls, Quality,Quality Controls
D002854 Chromatography, Paper An analytical technique for resolution of a chemical mixture into its component compounds. Compounds are separated on an adsorbent paper (stationary phase) by their varied degree of solubility/mobility in the eluting solvent (mobile phase). Paper Chromatography,Chromatographies, Paper,Paper Chromatographies
D002855 Chromatography, Thin Layer Chromatography on thin layers of adsorbents rather than in columns. The adsorbent can be alumina, silica gel, silicates, charcoals, or cellulose. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Chromatography, Thin-Layer,Thin Layer Chromatography,Chromatographies, Thin Layer,Chromatographies, Thin-Layer,Thin Layer Chromatographies,Thin-Layer Chromatographies,Thin-Layer Chromatography
D000438 Alcohols Alkyl compounds containing a hydroxyl group. They are classified according to relation of the carbon atom: primary alcohols, R-CH2OH; secondary alcohols, R2-CHOH; tertiary alcohols, R3-COH. (From Grant & Hackh's Chemical Dictionary, 5th ed)

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