5-Deoxy-5-C-(5-ethoxycarbonyl-1,2,3,- triazol-1-yl)-1,2-O-isopropylidene-alpha-D-xylofuranose. 1997

D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
Department of Chemistry, American University, NW, Washington, DC 20016-8014, USA.

Two unrelated molecules of the title compound, ethyl 1-(5-deoxy-1,2-O-isopropylidene-alpha-D-xylofuranos-5-C- yl)-1,2,3-triazole-5-carboxylate, C13H19N3O6, that are not linked by hydrogen bonding, comprise the asymmetric unit. There are no unusual bond lengths or angles. The two molecules differ in the degree of rotation around the methylene C atom that joins the triazole ring to the sugar part of the molecule. Molecules of the same conformation form infinite chains joined by hydrogen bonding between a H atom on the hydroxyl group of one molecule and an N atom in the triazole ring of another molecule generated by the 2(1) screw axis. Relevant intermolecular N...O distances are 3.013 (3) and 2.806 (3) A.

UI MeSH Term Description Entries
D003460 Crystallization The formation of crystalline substances from solutions or melts. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Crystalline Polymorphs,Polymorphism, Crystallization,Crystal Growth,Polymorphic Crystals,Crystal, Polymorphic,Crystalline Polymorph,Crystallization Polymorphism,Crystallization Polymorphisms,Crystals, Polymorphic,Growth, Crystal,Polymorph, Crystalline,Polymorphic Crystal,Polymorphisms, Crystallization,Polymorphs, Crystalline
D006860 Hydrogen Bonding A low-energy attractive force between hydrogen and another element. It plays a major role in determining the properties of water, proteins, and other compounds. Hydrogen Bonds,Bond, Hydrogen,Hydrogen Bond
D014994 Xylose D-Xylose,D Xylose

Related Publications

D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
September 2006, The Journal of organic chemistry,
D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
December 2015, Acta crystallographica. Section E, Crystallographic communications,
D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
November 2012, Acta crystallographica. Section E, Structure reports online,
D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
November 2012, Acta crystallographica. Section E, Structure reports online,
D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
January 2000, Carbohydrate research,
D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
May 1975, Carbohydrate research,
D Horton, and B R Levine, and P Norris, and R L Luck, and J V Silverton
October 2013, Acta crystallographica. Section E, Structure reports online,
Copied contents to your clipboard!