-transparent.png){kind=logo}
In a case of toxicological analysis by gas chromatography (GC)-mass spectrometry-data system, chemical ionization (CI), field ionization (FI) and electron impact data are shown to lead rapidly to assignments for all significant GC peaks. Valuable data include not only full spectra in the three ionization modes, but also exact mass measurements in the FI or CI mode. Such measurements, obtained by a dynamic peak-matching technique, lead to the elemental composition of the compounds of interest. This knowledge makes the assignment of key GC peaks unequivocal and provides an extremely high level of confidence regarding the identity of whole metabolite series. It is also shown that the nature of the FI information is very similar to that obtained from CI data.
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
November 2015,
Journal of the American Society for Mass Spectrometry,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
November 1978,
Biomedical mass spectrometry,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
July 1976,
Journal of biochemistry,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
October 1979,
Journal of chromatography,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
May 1998,
Journal of chromatography. A,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
January 2006,
Rapid communications in mass spectrometry : RCM,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
August 1977,
Biomedical mass spectrometry,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
June 2009,
Journal of chromatography. A,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
September 1979,
Journal of chromatography,
A Zune, and
P Dobberstein, and
K H Maurer, and
U Rapp
June 1984,
Analytical chemistry,
