Analysis of dissolved methane, ethane, and ethylene in ground water by a standard gas chromatographic technique. 1998

D H Kampbell, and S A Vandegrift
U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Ada, OK 74820, USA.

The measurement of dissolved gases such as methane, ethane, and ethylene in ground water is important in determining whether intrinsic bioremediation is occurring in a fuel- or solvent-contaminated aquifer. A simple procedure is described for the collection and subsequent analysis of ground water samples for these analytes. A helium headspace is generated above a water-filled bottle. Gases that are dissolved in the water partition between the gas and liquid phases and equilibrate rapidly. An aliquot of this headspace is analyzed by gas chromatography to determine the gases concentration in this phase. The concentration of the gas dissolved in the water can then be calculated based on its partitioning properties, as indicated by its Henry's Law constant.

UI MeSH Term Description Entries
D008697 Methane The simplest saturated hydrocarbon. It is a colorless, flammable gas, slightly soluble in water. It is one of the chief constituents of natural gas and is formed in the decomposition of organic matter. (Grant & Hackh's Chemical Dictionary, 5th ed)
D010937 Plant Growth Regulators Any of the hormones produced naturally in plants and active in controlling growth and other functions. There are three primary classes: auxins, cytokinins, and gibberellins. Phytohormone,Phytohormones,Plant Growth Regulator,Plant Hormone,Plant Hormones,Growth Regulators, Plant,Regulators, Plant Growth,Growth Regulator, Plant,Hormone, Plant,Hormones, Plant,Regulator, Plant Growth
D002849 Chromatography, Gas Fractionation of a vaporized sample as a consequence of partition between a mobile gaseous phase and a stationary phase held in a column. Two types are gas-solid chromatography, where the fixed phase is a solid, and gas-liquid, in which the stationary phase is a nonvolatile liquid supported on an inert solid matrix. Chromatography, Gas-Liquid,Gas Chromatography,Chromatographies, Gas,Chromatographies, Gas-Liquid,Chromatography, Gas Liquid,Gas Chromatographies,Gas-Liquid Chromatographies,Gas-Liquid Chromatography
D004980 Ethane A two carbon alkane with the formula H3C-CH3.
D005030 Ethylenes Derivatives of ethylene, a simple organic gas of biological origin with many industrial and biological use.
D005618 Fresh Water Water containing no significant amounts of salts, such as water from RIVERS and LAKES. Freshwater,Fresh Waters,Freshwaters,Water, Fresh,Waters, Fresh
D014873 Water Pollutants Substances or organisms which pollute the water or bodies of water. Use for water pollutants in general or those for which there is no specific heading. Water Pollutant,Pollutant, Water,Pollutants, Water

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