First High-Resolution Study of the 13CHD3 Infrared Spectrum: Rotational Analysis of the Ground State and the Fundamentals nu5 and nu3/nu6. 1998

Ulenikov, and Onopenko, and Alanko, and Koivusaari, and Anttila
Physics Department, Tomsk State University, Tomsk, 634050, Russia

The rotational structure in three fundamental bands nu3, nu5, and nu6 of 13CHD3 has been analyzed. As this study evidently is the first high-resolution investigation on the spectrum of this molecule, the determination of the ground state rotational constants was the necessary first step. The nu5 band (1290.536 cm-1) could be treated as an isolated band whereas it was necessary to analyze the bands nu3 (994.713 cm-1) and nu6 (1030.243 cm-1) simultaneously because of very strong interactions. The total number of assigned lines was 1116. The spectral region 850-1530 cm-1 was measured on a Fourier transform spectrometer and the 13C species was in natural abundance in CHD3. Copyright 1998 Academic Press.

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