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High Frequency Transitions in the Rotational Spectrum of SO2. 1998

Belov, and Tretyakov, and Kozin, and Klisch, and Winnewisser, and Lafferty, and Flaud
Institute of Applied Physics of Russian Academy of Sciences, 46 Uljanova Street, Nizhnii Novgorod, 603 600, Russia

A large number of rotational transitions of 32S16O2, 34S16O2, and 32S18O16O have been measured in the mm-, submm-, and terahertz ( approximately 1 THz) spectral regions. These data sets have been combined with all previously measured SO2 microwave and selected far infrared data to obtain a highly precise set of ground state rotational constants for these isotopomers. The rotational constants for the three isotopomers are in MHz as follows: Parameter32S16O234S16O232S18O16O A60778.54977 (44)58991.18295 (51)59101.1690 (27) B10318.07348 (7)10318.50993 (9)9724.64284 (56) C8799.703399 (70)8761.302481 (97)8331.56018 (51) Centrifugal distortion constants up to P10 are included in the fit. A frequency listing of all the data used in the frequency range between about 7 GHz and 1 THz is included. Copyright 1998 Academic Press.

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