[Studies on high temperature oxidation of noble metal alloys for dental use. (II) Effects of high temperature oxidation on casting (author's transl)]. 1976

H Ohno

The specimens which were cast from commercial alloys were polished metallographically and then oxidized at 800 degrees C for 1 hour in air. The results obtained were as follows: 1. The reduction rate of Cu aginast the original Cu amount in the alloy is given by the following equation: (see article) where S is surface area of the casting, KW is oxidation rate constant, t is time, Wc is weight of the casting, Ccu is weight percent of Cu, and n is between 1 and 2. 2. Owing to decrease of the Cu concentration in the outer layer of the alloy, the age-hardening did not appear in that layer. 3. Reflexibility of the polished surface of alloys became lower than that of the matrix due to precipitation of the oxide particles. 4. Hardness numbers of the internal oxidation zone (oxide particles, ZnO) decreased to 1/2 of the matrix. 5. The surface roughness of specimens after pickling was affected by the shape of oxide particles in the internal oxidation zone and varied with the different commercial alloys. 6. The dimensional change of casting due to oxidation is given by the following equation: (see article) where sigmacu is density of copper, KW is oxidation rate constant, t is time and n is between 1 and 2.

UI MeSH Term Description Entries
D010084 Oxidation-Reduction A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs (Lehninger, Principles of Biochemistry, 1982, p471). Redox,Oxidation Reduction
D003300 Copper A heavy metal trace element with the atomic symbol Cu, atomic number 29, and atomic weight 63.55. Copper-63,Copper 63
D006047 Gold Alloys Alloys that contain a high percentage of gold. They are used in restorative or prosthetic dentistry. Gold Alloy,Alloy, Gold,Alloys, Gold
D006244 Hardness The mechanical property of material that determines its resistance to force. HARDNESS TESTS measure this property. Hardnesses
D006358 Hot Temperature Presence of warmth or heat or a temperature notably higher than an accustomed norm. Heat,Hot Temperatures,Temperature, Hot,Temperatures, Hot

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