Spontaneous polymerisation on amphibole asbestos: relevance to asbestos removal. 2001

I Fenoglio, and M Tomatis, and B Fubini
Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali and Interdepartmental Center G. Scansetti for Studies on Asbestos and other Toxic Particulates, Università di Torino, Via P. Giuria 7, Torino, Italy. fubini@ch.unito.it

Taking advantage of the spontaneous polymerisation of eugenol to lignin-like species catalysed by the surface of crocidolite fibres, a procedure is proposed, possibly useful in asbestos removal and disposal, where the polymer avoids the release of airborne fibres and also scavenges ROS (reactive oxygen species).

UI MeSH Term Description Entries
D011108 Polymers Compounds formed by the joining of smaller, usually repeating, units linked by covalent bonds. These compounds often form large macromolecules (e.g., BIOPOLYMERS; PLASTICS). Polymer
D005054 Eugenol A cinnamate derivative of the shikimate pathway found in CLOVE OIL and other PLANTS. Phenol, 2-methoxy-4-(2-propenyl)-
D000393 Air Pollutants Any substance in the air which could, if present in high enough concentration, harm humans, animals, vegetation or materials. Substances include GASES; PARTICULATE MATTER; and volatile ORGANIC CHEMICALS. Air Pollutant,Air Pollutants, Environmental,Environmental Air Pollutants,Environmental Pollutants, Air,Air Environmental Pollutants,Pollutant, Air,Pollutants, Air,Pollutants, Air Environmental,Pollutants, Environmental Air
D017382 Reactive Oxygen Species Molecules or ions formed by the incomplete one-electron reduction of oxygen. These reactive oxygen intermediates include SINGLET OXYGEN; SUPEROXIDES; PEROXIDES; HYDROXYL RADICAL; and HYPOCHLOROUS ACID. They contribute to the microbicidal activity of PHAGOCYTES, regulation of SIGNAL TRANSDUCTION and GENE EXPRESSION, and the oxidative damage to NUCLEIC ACIDS; PROTEINS; and LIPIDS. Active Oxygen Species,Oxygen Radical,Oxygen Radicals,Pro-Oxidant,Reactive Oxygen Intermediates,Active Oxygen,Oxygen Species, Reactive,Pro-Oxidants,Oxygen, Active,Pro Oxidant,Pro Oxidants,Radical, Oxygen
D017636 Asbestos, Amphibole A class of asbestos that includes silicates of magnesium, iron, calcium, and sodium. The fibers are generally brittle and cannot be spun, but are more resistant to chemicals and heat than ASBESTOS, SERPENTINE. (From Hawley's Condensed Chemical Dictionary, 11th ed) Amphibole,Amphibole Asbestos,Amphiboles,Asbestos, Amphibole-group Minerals,Asbestos, Amphibole group Minerals

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