Molecular recognition in a uradinyl-functionalized stable radical. 2005

Patrick Taylor, and Paul M Lahti, and Joseph B Carroll, and Vincent M Rotello
Department of Chemistry, University of Massachusetts, Amherst, MA 01003, USA.

Stable radical 2-(6-uradinyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl (1) binds to hydrogen-bonding complement 2,6-di(propylamido)pyridine (DAP) in chloroform with Ka=220 M(-1) at 33 degrees C; ESI-MS shows not only 1:DAP complementary dyad formation, but also 1:(DAP)2 formation at higher concentrations of DAP.

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