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The study examined the usefulness of a Fenton-like system for the degradation of ionic liquid residues in water. The ionic liquid was oxidized in a dilute aqueous solution of 1-butyl-3-methylimidazolium chloride (bmimCl). The ionic liquid decomposes readily and rapidly in aqueous solution by chemical degradation in a Fenton-like system. Under chosen conditions the initial bmimCl solution was reduced by a factor of 0.973 within 90 min. Additional results showed that bmimCl degradations in a Fenton-like system in excess H2O2 could be interpreted as a combined oxidation-reduction mechanism. Preliminary investigations of the mechanism of such degradations have indicated that initial OH* radicals can attack any one of the three carbon atoms on the imidazolium ring. The intermediates of this reaction may be mono- di- or amino- carboxylic acids.
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
June 2014,
Journal of molecular modeling,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
September 2012,
Carbohydrate polymers,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
January 2010,
ChemSusChem,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
November 2012,
Carbohydrate polymers,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
April 2013,
Carbohydrate polymers,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
May 2007,
Radiation research,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
March 2011,
Bioresource technology,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
April 2012,
The journal of physical chemistry. B,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
January 2003,
Analytical and bioanalytical chemistry,
E M Siedlecka, and
W Mrozik, and
Z Kaczyński, and
P Stepnowski
October 2010,
Physical chemistry chemical physics : PCCP,
