Biomaterial Database

Cellulose/polycaprolactone blends regenerated from ionic liquid 1-butyl-3-methylimidazolium chloride. 2012

Renyan Xiong, and Nishar Hameed, and Qipeng Guo

Polymers Research Group, Institute for Frontier Materials, Deakin University, Geelong, Victoria 3216, Australia.

Ionic liquid solvent, 1-butyl-3-methylimidazolium chloride (BMIM[Cl]) was used to prepare cellulose/polycaprolactone (PCL) blend films. This solvent was recycled with high yield and purity after blend precipitation. The inter- and intra-molecular hydrogen bonding interactions in these blends were investigated by Fourier transform infrared (FTIR) spectroscopy and it was found that a new peak in the carbonyl region, assigned to hydrogen bonding between carbonyl groups of PCL and hydroxyl groups of cellulose in blends with PCL composition less than 40 wt%. Differential scanning calorimetry (DSC) results implied a partial miscibility of the two components by melting point depression. Moreover, the tensile properties of the blends can be adjusted by incorporating various amounts of PCL into cellulose. The blends show significant enhancement of thermal stability compared to the regenerated cellulose when the content of PCL is higher than 40 wt%. This work demonstrates an effective approach for the processing biodegradable blends from natural and synthetic polymers.

UI	MeSH Term	Description	Entries
D007093	Imidazoles	Compounds containing 1,3-diazole, a five membered aromatic ring containing two nitrogen atoms separated by one of the carbons. Chemically reduced ones include IMIDAZOLINES and IMIDAZOLIDINES. Distinguish from 1,2-diazole (PYRAZOLES).
D008422	Materials Testing	The testing of materials and devices, especially those used for PROSTHESES AND IMPLANTS; SUTURES; TISSUE ADHESIVES; etc., for hardness, strength, durability, safety, efficacy, and biocompatibility.	Biocompatibility Testing,Biocompatible Materials Testing,Hemocompatibility Testing,Testing, Biocompatible Materials,Testing, Hemocompatible Materials,Hemocompatibility Testings,Hemocompatible Materials Testing,Materials Testing, Biocompatible,Materials Testing, Hemocompatible,Testing, Biocompatibility,Testing, Hemocompatibility,Testing, Materials,Testings, Biocompatibility
D011091	Polyesters	Polymers of organic acids and alcohols, with ester linkages--usually polyethylene terephthalate; can be cured into hard plastic, films or tapes, or fibers which can be woven into fabrics, meshes or velours.	Polyester
D002152	Calorimetry, Differential Scanning	Differential thermal analysis in which the sample compartment of the apparatus is a differential calorimeter, allowing an exact measure of the heat of transition independent of the specific heat, thermal conductivity, and other variables of the sample.	Differential Thermal Analysis, Calorimetric,Calorimetric Differential Thermal Analysis,Differential Scanning Calorimetry,Scanning Calorimetry, Differential
D002482	Cellulose	A polysaccharide with glucose units linked as in CELLOBIOSE. It is the chief constituent of plant fibers, cotton being the purest natural form of the substance. As a raw material, it forms the basis for many derivatives used in chromatography, ion exchange materials, explosives manufacturing, and pharmaceutical preparations.	Alphacel,Avicel,Heweten,Polyanhydroglucuronic Acid,Rayophane,Sulfite Cellulose,alpha-Cellulose,Acid, Polyanhydroglucuronic,alpha Cellulose
D013718	Tensile Strength	The maximum stress a material subjected to a stretching load can withstand without tearing. (McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed, p2001)	Strength, Tensile,Strengths, Tensile,Tensile Strengths
D017550	Spectroscopy, Fourier Transform Infrared	A spectroscopic technique in which a range of wavelengths is presented simultaneously with an interferometer and the spectrum is mathematically derived from the pattern thus obtained.	FTIR,Fourier Transform Infrared Spectroscopy,Spectroscopy, Infrared, Fourier Transform
D052578	Ionic Liquids	Salts that melt below 100 C. Their low VOLATILIZATION can be an advantage over volatile organic solvents.	Ionic Liquid,Ionic Solvents,Liquid, Ionic,Liquids, Ionic,Solvents, Ionic