BIOMAT Database Logo BIOMAT Database Logo

One-pot formation of allylic chlorides from carbonyl derivatives. 2008

Matthew J Fuchter, and Jean-Noël Levy
Department of Chemistry, Imperial College London, London SW7 2AZ. m.fuchter@imperial.ac.uk

An efficient, one-pot method for the conversion of carbonyl electrophiles to allylic chlorides has been developed, by activating magnesium alkoxides in situ using TiCl4.

UI MeSH Term Description Entries
D002255 Carbonic Acid Carbonic acid (H2C03). The hypothetical acid of carbon dioxide and water. It exists only in the form of its salts (carbonates), acid salts (hydrogen carbonates), amines (carbamic acid), and acid chlorides (carbonyl chloride). (From Grant & Hackh's Chemical Dictionary, 5th ed) Acid, Carbonic
D015394 Molecular Structure The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds. Structure, Molecular,Molecular Structures,Structures, Molecular
D017606 Chlorine Compounds Inorganic compounds that contain chlorine as an integral part of the molecule. Chlorine Compounds, Inorganic,Compounds, Chlorine,Compounds, Inorganic Chlorine,Inorganic Chlorine Compounds

Related Publications

Matthew J Fuchter, and Jean-Noël Levy
A one-pot access to cyclopropanes from allylic ethers via hydrozirconation-deoxygenative ring formation.
June 2002, Chemical communications (Cambridge, England),
Matthew J Fuchter, and Jean-Noël Levy
Generation of allylic indium by hydroindation of 1,3-dienes and one-pot reaction with carbonyl compounds.
September 2006, Organic letters,
Matthew J Fuchter, and Jean-Noël Levy
One-pot preparation of 1-chlorovinylisocyanides from carbonyl compounds.
August 1987, The Journal of antibiotics,
Matthew J Fuchter, and Jean-Noël Levy
Copper-catalyzed one-pot trifluoromethylation/aryl migration/carbonyl formation with homopropargylic alcohols.
July 2014, Angewandte Chemie (International ed. in English),
Matthew J Fuchter, and Jean-Noël Levy
Zn/Sc bimetallic relay catalysis: one pot cycloisomerization/carbonyl-ene reaction toward oxazole derivatives.
January 2016, Organic & biomolecular chemistry,
Matthew J Fuchter, and Jean-Noël Levy
One-pot thioether formation from S-nitrosothiols.
December 2010, Organic letters,
Matthew J Fuchter, and Jean-Noël Levy
Dihydropyrrole-3-thiones: one-pot synthesis from propargylamines, acyl chlorides and sodium sulfide.
August 2023, Organic & biomolecular chemistry,
Matthew J Fuchter, and Jean-Noël Levy
One-Pot Synthesis of Lactose Derivatives from Whey Permeate.
June 2020, Foods (Basel, Switzerland),
Matthew J Fuchter, and Jean-Noël Levy
One-pot synthesis of multisubstituted propenylbenzenes from benzyl chlorides through relay catalysis of palladium.
July 2023, Organic & biomolecular chemistry,
Matthew J Fuchter, and Jean-Noël Levy
trans-hydroalumination/alkylation: one-pot synthesis of trisubstituted allylic alcohols.
August 2006, Organic letters,
Copied contents to your clipboard!