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One-dimensional metal-azido complex constructed by a double EO azido bridged trinuclear nickel(II) unit: synthesis, structure and magnetic properties. 2010

Fu-Chen Liu, and Jiong-Peng Zhao, and Bo-Wen Hu, and Yong-Fei Zeng, and J Ribas, and Xian-He Bu
Department of Chemistry, Nankai University, Tianjin 300071, China.

The hydrothermal reaction of Ni(NO(3))(2).6H(2)O, NaN(3) phenanthroline and nicotinic acid yielded a one-dimensional (1D) complex, [Ni(1.5)(N(3))(2)(phen)(nic)](n) (1) (phen = phenanthroline, nic = nicotinate), which is a new example of the named orbital countercomplementarity-like complex. In 1, the nicotinate shows mu(3)-nic-N,O,O coordination mode, and the azide groups adopt mu(1,1) bridging mode linking Ni(II) ions to form a rare trinuclear Ni(II) unit bridged by a double mu(1,1) azido.

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