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Rhodium-catalyzed direct ortho C-H olefination of phenol derivatives. 2011

Chao Feng, and Teck-Peng Loh
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637616.

Cationic rhodium complex-catalyzed olefination of phenol derivatives for the direct introduction of an α,β-unsaturated ester appendage is described. In addition, deuterium labelling and kinetic isotope effect studies were performed to probe the reaction mechanism.

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