BIOMAT Database Logo BIOMAT Database Logo

Poly(allyl glycidyl ether)-A versatile and functional polyether platform. 2011

Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Materials Research Laboratory, University of California, Santa Barbara, CA, 93106.

Allyl glycidyl ether, polymerized from potassium alkoxide/naphthalenide initiators under both neat and solution conditions was shown to be a highly-controlled process. In both cases, molar masses (10-100 kg/mol) were determined by the reaction stoichiometry, and low polydispersity indices (1.05-1.33) could be obtained with a full understanding of the dominant side reaction, isomerization of the allyl side chain, being developed. The degree of isomerization of allyl to cis-prop-1-enyl ether groups (0 - 10 % mol.) was not correlated to the molar mass or polydispersity of the polymer but was dictated by the polymerization temperature. This allows the extent of isomerization to be reduced to essentially zero under either melt or solution conditions at polymerization temperatures of less than 40 °C.

UI MeSH Term Description Entries

Related Publications

Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
DNA adduct formation by allyl glycidyl ether.
July 1996, Carcinogenesis,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Newly developed poly(allyl glycidyl ether/divinyl benzene) polymer for phosphopeptides enrichment and desalting of biofluids.
March 2014, ACS applied materials & interfaces,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Nasal and pulmonary toxicity of allyl glycidyl ether in mice.
December 1987, Toxicology letters,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Synthesis of Poly(allyl glycidyl ether)-Derived Polyampholytes and Their Application to the Cryopreservation of Living Cells.
March 2023, Biomacromolecules,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Poly(N-allyl acrylamide) as a Reactive Platform toward Functional Hydrogels.
January 2023, ACS macro letters,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Hybrid inorganic-organic framework as efficient heterogeneous catalyst for the synthesis of allyl glycidyl carbonate from CO2 and allyl glycidyl ether.
March 2013, Journal of nanoscience and nanotechnology,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Immobilization of Candida rugosa lipase on poly(allyl glycidyl ether-co-ethylene glycol dimethacrylate) macroporous polymer particles.
June 2008, Bioresource technology,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Miscible Polyether/Poly(ether-acetal) Electrolyte Blends.
January 2020, Macromolecules,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Electron stimulated desorption of anions and cations from condensed allyl glycidyl ether.
July 2010, Physical chemistry chemical physics : PCCP,
Bongjae F Lee, and Matthew J Kade, and Jerred A Chute, and Nalini Gupta, and Luis M Campos, and Glenn H Fredrickson, and Edward J Kramer, and Nathaniel A Lynd, and Craig J Hawker
Fabrication of monodisperse poly (allyl glycidyl ether-co-divinyl benzene) microspheres and their application in anion-exchange stationary phase.
June 2019, Journal of chromatography. A,
Copied contents to your clipboard!