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Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones. 2017
Department of Chemistry, K. N. Toosi University of Technology, P.O. Box 16315-1618, 15418 Tehran, Iran. v.khakyzadeh@kntu.ac.ir.
A rhodium-catalyzed regioselective addition of sulfonyl hydrazides to allenes is reported. With Rh(i)/DPEphos/benzoic acid as the catalyst system, branched allylic sulfones can be obtained, in good to excellent yields and regioselectivities.
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