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Palladium-catalyzed direct sulfonylation of C-H bonds with the insertion of sulfur dioxide. 2017
Department of Biochemistry and Molecular Biology, Zhejiang University School of Medicine, Hangzhou 310058, P. R. China. hongguangxia@zju.edu.cn.
A palladium-catalyzed direct sulfonylation of C-H bonds with the insertion of sulfur dioxide under mild conditions is reported. The sulfonylative couplings with the insertion of sulfur dioxide into C-H bonds are effective, and two classes of sulfonylative products are formed in moderate to good yields by the combination of radical chemistry and palladium-catalyzed C-H activation.
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