BIOMAT Database Logo BIOMAT Database Logo

Versatile Fabrication Approach of Conductive Hydrogels via Copolymerization with Vinyl Monomers. 2017

Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad

Functionalized poly(ethylene dioxythiophene) (f-PEDOT) was copolymerized with two vinyl monomers of different hydrophilicity, acrylic acid and hydroxyethyl methacrylate, to produce electroconductive hydrogels with a range of physical and electronic properties. These hydrogels not only possessed tailored physical properties, such as swelling ratios and mechanical properties, but also displayed electroactivity dependent on the chemical composition of the network. Raman spectroscopy indicated that the functional PEDOT in the hydrogels is in an oxidized form, most likely accounting for the good electrochemical response of the hydrogels observed in physiological buffer. In vitro cell studies showed that cardiac cells respond differently when seeded on hydrogel substrates with different compositions. This study presents a facile approach for the fabrication of electroconductive hydrogels with a range of properties, paving the way for scaffolds that can meet the requirements of different electroresponsive tissues.

UI MeSH Term Description Entries

Related Publications

Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Copolymerization of ethylene with non-vinyl polar monomers.
January 2022, Proceedings of the Japan Academy. Series B, Physical and biological sciences,
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Insertion Copolymerization of Difunctional Polar Vinyl Monomers with Ethylene.
September 2015, ACS macro letters,
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers.
January 2021, Colloid and polymer science,
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Coordination copolymerization of polar vinyl monomers H2C=CHX.
January 2008, Angewandte Chemie (International ed. in English),
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Formation of alternating copolymers via spontaneous copolymerization of 1,3-dehydroadamantane with electron-deficient vinyl monomers.
July 2006, Journal of the American Chemical Society,
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Coordination-insertion copolymerization of polar vinyl monomers by palladium catalysts.
October 2010, Chemical record (New York, N.Y.),
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Reactivity of vinyl ethers and vinyl ribosides in UV-initiated free radical copolymerization with acceptor monomers.
September 2010, Biomacromolecules,
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Fabrication of conductive gelatin methacrylate-polyaniline hydrogels.
March 2016, Acta biomaterialia,
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
Mechanistic insights on the copolymerization of polar vinyl monomers with neutral Ni(II) catalysts.
September 2009, Journal of the American Chemical Society,
Lin Jiang, and Carmine Gentile, and Antonio Lauto, and Chen Cui, and Yihui Song, and Tony Romeo, and Saimon M Silva, and Owen Tang, and Poonam Sharma, and Gemma Figtree, and J Justin Gooding, and Damia Mawad
A Versatile Ligand Platform for Palladium- and Nickel-Catalyzed Ethylene Copolymerization with Polar Monomers.
March 2018, Angewandte Chemie (International ed. in English),
Copied contents to your clipboard!