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Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers. 2021
Giuseppe Trusiano, and
Alessandra Vitale, and
Céline Bonneaud, and
Diego Pugliese, and
Sara Dalle Vacche, and
Christine Joly-Duhamel, and
Chadron M Friesen, and
Roberta Bongiovanni
Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.
New perfluoropolyalkylether (PFPAE) monomers, chain extended with different alkyl groups and functionalized with vinyl ether or epoxide end-groups, were employed, together with trimethylolpropane trivinyl ether or trimethylolpropane triglycidyl ether, to produce fluorinated copolymers. The photoinduced cationic polymerization was investigated, and the PFPAE-based copolymer properties were thoroughly characterized. Interesting surface properties and two different values of refractive index were observed: thus, these fluorinated copolymers can be suitable materials for the manufacture of self-cleaning coatings and optical waveguides.
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