Electron transfer reaction of cytochrome c peroxidase at tin oxide electrodes. 1986

H Assefa, and E F Bowden

The unmediated one-electron reduction and reoxidation of ferric cytochrome c peroxidase at fluoride-doped tin oxide electrodes is reported. A long range interfacial electron transfer distance of 17 A is postulated by analogy to the Poulos/Kraut model for the cytochrome c peroxidase/cytochrome c electron transfer complex. The utility of the interfacial electrochemical approach for investigating cytochrome c peroxidase electron transfer behavior is discussed.

UI MeSH Term Description Entries
D008433 Mathematics The deductive study of shape, quantity, and dependence. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 6th ed) Mathematic
D010087 Oxides Binary compounds of oxygen containing the anion O(2-). The anion combines with metals to form alkaline oxides and non-metals to form acidic oxides. Oxide
D010544 Peroxidases Ovoperoxidase
D003578 Cytochrome-c Peroxidase A hemeprotein which catalyzes the oxidation of ferrocytochrome c to ferricytochrome c in the presence of hydrogen peroxide. EC 1.11.1.5. Cytochrome Peroxidase,Cytochrome c-551 Peroxidase,Cytochrome c 551 Peroxidase,Cytochrome c Peroxidase,Peroxidase, Cytochrome,Peroxidase, Cytochrome c-551,Peroxidase, Cytochrome-c
D004563 Electrochemistry The study of chemical changes resulting from electrical action and electrical activity resulting from chemical changes. Electrochemistries
D004566 Electrodes Electric conductors through which electric currents enter or leave a medium, whether it be an electrolytic solution, solid, molten mass, gas, or vacuum. Anode,Anode Materials,Cathode,Cathode Materials,Anode Material,Anodes,Cathode Material,Cathodes,Electrode,Material, Anode,Material, Cathode
D004579 Electron Transport The process by which ELECTRONS are transported from a reduced substrate to molecular OXYGEN. (From Bennington, Saunders Dictionary and Encyclopedia of Laboratory Medicine and Technology, 1984, p270) Respiratory Chain,Chain, Respiratory,Chains, Respiratory,Respiratory Chains,Transport, Electron
D012441 Saccharomyces cerevisiae A species of the genus SACCHAROMYCES, family Saccharomycetaceae, order Saccharomycetales, known as "baker's" or "brewer's" yeast. The dried form is used as a dietary supplement. Baker's Yeast,Brewer's Yeast,Candida robusta,S. cerevisiae,Saccharomyces capensis,Saccharomyces italicus,Saccharomyces oviformis,Saccharomyces uvarum var. melibiosus,Yeast, Baker's,Yeast, Brewer's,Baker Yeast,S cerevisiae,Baker's Yeasts,Yeast, Baker
D014001 Tin A trace element that is required in bone formation. It has the atomic symbol Sn, atomic number 50, and atomic weight 118.71. Stannum

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