Removal of inert COD and trace metals from stabilized landfill leachate by granular activated carbon (GAC) adsorption. 2018

Ehsan Mohammad-Pajooh, and Ariel E Turcios, and Graham Cuff, and Dirk Weichgrebe, and Karl-Heinz Rosenwinkel, and M D Vedenyapina, and L R Sharifullina
Institute for Sanitary Engineering and Waste Management, Leibniz University Hannover, Appelstr. 9a, D-30167 Hannover, Germany. Electronic address: pajooh@isah.uni-hannover.de.

Landfills in Germany are currently approaching stabilization phase; as a result removal of inert organics and potentially toxic elements in the leachate is becoming a primary concern. Dissolved air floatation (DAF) at the secondary stage reduces only 27% of the residual chemical oxygen demand (COD) in the investigated treatment systems; downstream granular activated carbon (GAC) units are required to further reduce COD concentration by 40-56% to meet indirect discharge or direct discharge limits respectively. Therefore, in this study performance in terms of COD and trace metals adsorption of different types of granular activated carbon were compared over different contact times and dosages. GAC 1 with Brunauer-Emmett-Teller (BET) surface area of 719.5 ± 2.1 m2/g and average pore diameter (D) of 4.81 nm was identified to be inappropriate for treatment of leachate from this landfill. GAC 2 (with BET of 1513.7 ± 6.4 m2/g and D of 3.50 nm) was feasible for COD reduction from DAF-pretreated leachate, while GAC 3 (with BET of 644.5 ± 2.6 m2/g and D of 5.65 nm) can be coupled either with biological step alone, or as a tertiary step after the DAF unit. Moreover, as COD is the primary remaining contaminant of interest after secondary and tertiary treatment, spectrometer probes provide a close estimation of COD concentration for use in online monitoring. Beside COD removal, GAC 3 also confirmed the effectiveness of trace metals adsorption even at trace level, as it removed 66, 64, 48, 47, 43, and 25% of copper, cobalt, chromium, manganese, nickel, and zinc, respectively.

UI MeSH Term Description Entries
D008670 Metals Electropositive chemical elements characterized by ductility, malleability, luster, and conductance of heat and electricity. They can replace the hydrogen of an acid and form bases with hydroxyl radicals. (Grant & Hackh's Chemical Dictionary, 5th ed) Metal
D002244 Carbon A nonmetallic element with atomic symbol C, atomic number 6, and atomic weight [12.0096; 12.0116]. It may occur as several different allotropes including DIAMOND; CHARCOAL; and GRAPHITE; and as SOOT from incompletely burned fuel. Carbon-12,Vitreous Carbon,Carbon 12,Carbon, Vitreous
D002606 Charcoal An amorphous form of carbon prepared from the incomplete combustion of animal or vegetable matter, e.g., wood. The activated form of charcoal is used in the treatment of poisoning. (Grant & Hackh's Chemical Dictionary, 5th ed) Activated Charcoal,Actidose,Actidose-Aqua,Adsorba,Carbomix,Charbon,CharcoAid,CharcoCaps,Charcodote,Formocarbine,Insta-Char,Kohle-Compretten,Kohle-Hevert,Kohle-Pulvis,Kohle-Tabletten Boxo-Pharm,Liqui-Char,Norit,Ultracarbon,Charcoal, Activated
D005858 Germany A country in central Europe, bordering the Baltic Sea and the North Sea, between the Netherlands and Poland, south of Denmark. The capital is Berlin.
D000327 Adsorption The adhesion of gases, liquids, or dissolved solids onto a surface. It includes adsorptive phenomena of bacteria and viruses onto surfaces as well. ABSORPTION into the substance may follow but not necessarily. Adsorptions
D014131 Trace Elements A group of chemical elements that are needed in minute quantities for the proper growth, development, and physiology of an organism. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Biometal,Biometals,Trace Element,Trace Mineral,Trace Minerals,Element, Trace,Elements, Trace,Mineral, Trace,Minerals, Trace
D057919 Biological Oxygen Demand Analysis Testing for the amount of biodegradable organic material in a water sample by measuring the quantity of oxygen consumed by biodegradation of those materials over a specific time period. Biological Oxygen Demand,Biological Oxygen Demand Analyses,Chemical Oxygen Demand,Chemical Oxygen Demand Analyses,Chemical Oxygen Demand Analysis,Demand, Chemical Oxygen,Oxygen Demand, Biological,Oxygen Demand, Chemical
D064091 Waste Disposal Facilities Sites that receive and store WASTE PRODUCTS. Some facilities also sort, process, and recycle specific waste products. Landfills,Waste Disposal Sites,Waste Dump Sites,Waste Dumping Grounds,Waste Dumping Sites,Waste Dumps,Disposal Facilities, Waste,Disposal Facility, Waste,Disposal Site, Waste,Disposal Sites, Waste,Dump Site, Waste,Dump Sites, Waste,Dump, Waste,Dumping Ground, Waste,Dumping Grounds, Waste,Dumping Site, Waste,Dumping Sites, Waste,Dumps, Waste,Facilities, Waste Disposal,Facility, Waste Disposal,Ground, Waste Dumping,Grounds, Waste Dumping,Landfill,Site, Waste Disposal,Site, Waste Dump,Site, Waste Dumping,Sites, Waste Disposal,Sites, Waste Dump,Sites, Waste Dumping,Waste Disposal Facility,Waste Disposal Site,Waste Dump,Waste Dump Site,Waste Dumping Ground,Waste Dumping Site

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