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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy. 2018
Thomas Dumas, and
Dominique Guillaumont, and
Philippe Moisy, and
David K Shuh, and
Tolek Tyliszczak, and
Pier Lorenzo Solari, and
Christophe Den Auwer
CEA, Nuclear Energy Division, Radiochemistry and Process Department, 30207 Bagnols-sur-Cèze, France. thomas.dumas@cea.fr.
In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs' valence orbitals are probed by soft X-ray absorption measurements.
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