Radiolysis of supercritical water at 400 °C: density dependence of the rate constant for the reaction of hydronium ions with hydrated electrons. 2019

Jintana Meesungnoen, and Jean-Paul Jay-Gerin
Département de Médecine Nucléaire et de Radiobiologie, Faculté de Médecine et des Sciences de la Santé, Université de Sherbrooke, 3001, 12ème Avenue Nord, Sherbrooke, Québec J1H 5N4, Canada. jean-paul.jay-gerin@USherbrooke.ca.

The rate constant, k(eaq- + H3O+), for the reaction of hydronium ions with hydrated electrons in supercritical water (SCW) at 400 °C has been evaluated as a function of water density using Monte Carlo track chemistry simulations of the radiolysis of SCW over the range of 0.15-0.6 g cm-3. Results are consistent with recent predictions using the so-called "cage effect" model.

UI MeSH Term Description Entries

Related Publications

Jintana Meesungnoen, and Jean-Paul Jay-Gerin
January 1967, International journal of radiation biology and related studies in physics, chemistry, and medicine,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
February 1973, Science (New York, N.Y.),
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
February 1977, Biochimica et biophysica acta,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
February 2005, The journal of physical chemistry. A,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
May 2010, Journal of the American Chemical Society,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
March 1983, Biochimica et biophysica acta,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
November 2010, The journal of physical chemistry. A,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
July 2020, The journal of physical chemistry. A,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
March 1991, International journal of radiation biology,
Jintana Meesungnoen, and Jean-Paul Jay-Gerin
November 1971, Biochemical and biophysical research communications,
Copied contents to your clipboard!