BIOMAT Database Logo BIOMAT Database Logo

Kinetic and mechanistic analysis of a synthetic reversible CO2/HCO2- electrocatalyst. 2020

Drew W Cunningham, and Jenny Y Yang
Department of Chemistry, University of California, Irvine, 92617, USA. j.yang@uci.edu.

[Pt(depe)2](PF6)2 electrocatalyzes the reversible conversion between CO2 and HCO2- with high selectivity and low overpotential but low rates. A comprehensive kinetic analysis indicates the rate determining step for CO2 reduction is the reactivity of a Pt hydride intermediate to produce HCO2-. To accelerate catalysis, the use of cationic and hydrogen-bond donor additives are explored.

UI MeSH Term Description Entries

Related Publications

Drew W Cunningham, and Jenny Y Yang
A simple kinetic method for rapid mechanistic analysis of reversible enzyme inhibitors.
August 2003, Assay and drug development technologies,
Drew W Cunningham, and Jenny Y Yang
Reversible inhibition of LCAT by penicillins. Kinetic and mechanistic investigations.
January 1978, Scandinavian journal of clinical and laboratory investigation. Supplementum,
Drew W Cunningham, and Jenny Y Yang
Kinetic and computational analysis of the reversible inhibition of porcine pancreatic elastase: a structural and mechanistic approach.
January 2016, Journal of enzyme inhibition and medicinal chemistry,
Drew W Cunningham, and Jenny Y Yang
CO2 reduction or HCO2- oxidation? Solvent-dependent thermochemistry of a nickel hydride complex.
June 2017, Chemical communications (Cambridge, England),
Drew W Cunningham, and Jenny Y Yang
Reducing CO2 to HCO2- at Mild Potentials: Lessons from Formate Dehydrogenase.
November 2020, Journal of the American Chemical Society,
Drew W Cunningham, and Jenny Y Yang
Mechanistic insights into CO2 conversion chemistry of copper bis-(terpyridine) molecular electrocatalyst using accessible operando spectrochemistry.
October 2022, Nature communications,
Drew W Cunningham, and Jenny Y Yang
Kinetic analysis and mechanistic aspects of autoxidation of catechins.
January 2002, Biochimica et biophysica acta,
Drew W Cunningham, and Jenny Y Yang
Mechanistic and microkinetic analysis of CO2 hydrogenation on ceria.
March 2016, Physical chemistry chemical physics : PCCP,
Drew W Cunningham, and Jenny Y Yang
The Reductive Activation of CO2 Across a Ti=Ti Double Bond: Synthetic, Structural, and Mechanistic Studies.
October 2015, Organometallics,
Drew W Cunningham, and Jenny Y Yang
Dynamic Kinetic Resolution Enabled by Intramolecular Benzoin Reaction: Synthetic Applications and Mechanistic Insights.
June 2016, Journal of the American Chemical Society,
Copied contents to your clipboard!