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A flexible microporous framework with temperature-dependent gate-opening behaviours for C2 gases. 2021

Zhenyu Ji, and Yerong Fan, and Mingyan Wu, and Maochun Hong
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.

Herein we report a two-fold interpenetrating pillar-layer microporous material, whose framework severely shrinks after losing guest molecules and transforms into a stable nonporous one. More importantly, the guest-free framework has rarely seen temperature-dependent gate-opening behaviours for C2 gases around room temperature.

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