New insights into quantifying the solvatochromism of BODIPY based fluorescent probes. 2021

Felix Y Telegin, and Yuriy S Marfin
Department of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology 7, Sheremetevsky Ave, Ivanovo 153000, Russia. Electronic address: telegin@isuct.ru.

A simple semiempiric phenomenological approach is developed for quantifying the solvent effect on the absorption and emission properties of BODIPYs. It is based on a new rule describing the linear relationship between the difference (Stokes shift) and the sum (double Gibbs free energy of electron transfer) for absorption and emission wavenumbers derived from a combination of solvent functions of Liptay theory. This rule is correspondent to changes of dipole moments in the ground and excited states. High reliability and advantages of the developed approach in comparison with traditional methods of the analysis of the solvatochromism based on Dimroth-Reichard and Lippert-Mataga solvent scales are illustrated for selected BODIPYs exhibiting positive, negative, and near-zero solvatochromism.

UI MeSH Term Description Entries

Related Publications

Felix Y Telegin, and Yuriy S Marfin
April 2020, Chemistry (Weinheim an der Bergstrasse, Germany),
Felix Y Telegin, and Yuriy S Marfin
May 2005, The Journal of organic chemistry,
Felix Y Telegin, and Yuriy S Marfin
February 1996, Cytometry,
Felix Y Telegin, and Yuriy S Marfin
January 2023, Current organic synthesis,
Felix Y Telegin, and Yuriy S Marfin
December 2015, Scientific reports,
Felix Y Telegin, and Yuriy S Marfin
March 2024, Chemical science,
Felix Y Telegin, and Yuriy S Marfin
October 2018, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,
Felix Y Telegin, and Yuriy S Marfin
July 2014, Chemical communications (Cambridge, England),
Felix Y Telegin, and Yuriy S Marfin
March 2013, Journal of materials chemistry. B,
Felix Y Telegin, and Yuriy S Marfin
February 2015, The journal of physical chemistry. B,
Copied contents to your clipboard!