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An (NH4)2S2O8-promoted cross-coupling of thiols/diselenides and sulfoxides for the synthesis of unsymmetrical disulfides/selenosulfides. 2022
Yang-Tong Ma, and
Chao Lin, and
Xiao-Bo Huang, and
Miao-Chang Liu, and
Yun-Bing Zhou, and
Hua-Yue Wu
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, P. R. China. mcl@wzu.edu.cn.
An (NH4)2S2O8-promoted cross-coupling of thiols/diselenides and sulfoxides to construct unsymmetrical disulfides/selenosulfides is disclosed. Control experiments demonstrate that (NH4)2S2O8 acts as an acid and an oxidant, while both ionic and radical routes are involved in the reaction. The KIE experiments reveal that C-H bond cleavage of sulfoxides was involved in the turnover-limiting step.
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