Recyclable, UV-shielding, and biodegradable chitosan-based cardanol glycidyl ether as excellent water and oil resistance as well as gas barrier coating for paper. 2023

Jihuai Tan, and Qinghao Zhu, and Dandan Li, and Nengkun Huang, and Ziwen Wang, and Zhulan Liu, and Yunfeng Cao
College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China; College of Light Industry and Food Science, Nanjing Forestry University, Nanjing 210037, China.

Developing a feasible and low-cost approach to fabricate recyclable, UV-shielding, biodegradable as well as water- and oil-resistant coating for paper substance is still a challenge. Herein, novel full-biobased chitosan-derived cardanol glycidyl ether (CS-xCGE, x = 1/8, 1/4, 1/2, and 1) coatings with different contents of cardanol glycidyl ether (CGE) were developed for paper substance via the ethoxylation of cardanol and sequent addition with chitosan in a one-pot process. Benefiting from the hydrophobicity and ultraviolet resistance of CGE, the resultant CS-CGE (x = 1) coated paper exhibited not only remarkable oil resistance (kit rating value of 11/12), but also water resistance (Cobb 60 value of 5.78 g/m2), UV shielding and excellent recyclability. Compared with the uncoated paper, the mechanical properties of CS-CGE coated paper including tensile strength, folding strength, and resistance of water vapor permeability were improved 25 %, 63 %, and 73.4 %, respectively, which could be ascribed to the flexible long-alkyl chain in the structure of CS-CGE and the continuous and homogeneous CS-CGE derived film covered in paper substance. Most importantly, CS-CGE film is biodegradable when it is only buried in soil. This study affords a feasible and sustainable strategy for large-scale fabrication of full-biobased, recyclable, UV-shielding, water and oil resistant, as well as biodegradable coating for green paper-derived packaging.

UI MeSH Term Description Entries
D004986 Ether A mobile, very volatile, highly flammable liquid used as an inhalation anesthetic and as a solvent for waxes, fats, oils, perfumes, alkaloids, and gums. It is mildly irritating to skin and mucous membranes. Diethyl Ether,Ether, Ethyl,Ethyl Ether,Ether, Diethyl
D004987 Ethers Organic compounds having two alkyl or aryl groups bonded to an oxygen atom, as in the formula R1–O–R2.
D005019 Ethyl Ethers Organic compounds having ethyl groups bound to an oxygen atom. Ethoxy Compounds,Compounds, Ethoxy,Ethers, Ethyl
D048271 Chitosan Deacetylated CHITIN, a linear polysaccharide of deacetylated beta-1,4-D-glucosamine. It is used in HYDROGEL and to treat WOUNDS. Poliglusam
D018857 Food Packaging Containers, packaging, and packaging materials for processed and raw foods and beverages. It includes packaging intended to be used for storage and also used for preparation of foods such as microwave food containers versus COOKING AND EATING UTENSILS. Packaging materials may be intended for food contact or designated non-contact, for example, shipping containers. FOOD LABELING is also available. Food Containers,Packaging, Food,Food Container

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