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Photo-Induced Carbonylation of Aryl Bromides for the Synthesis of Aryl Esters and Amides Under Transition Metal-Free Conditions. 2023

Yan Zheng, and Bing-Hong Teng, and Youcan Zhang, and Xiao-Feng Wu
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese, Academy of Sciences, 116023, Dalian, Liaoning, China.

In this work, we developed a photo-induced carbonylation of aryl bromides under transition metal-free conditions. The reaction shows good activity with alcohol and amine nucleophiles. Various esters and amides were formed from aryl halides and alcohols and amines under mild conditions in moderate to good yields.

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