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Cobalt(III)-Catalyzed Aryl and Alkenyl C-H Aminocarbonylation with Isocyanates and Acyl Azides. 2015

Jie Li, and Lutz Ackermann
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/

Expedient C-H aminocarbonylations of unactivated (hetero)arenes and alkenes were accomplished with a cobalt(III) catalyst that shows high functional group tolerance. The C-H functionalization occurred with excellent chemo-, site-, and diastereoselectivity and enabled step-economical reactions with isocyanates or acyl azides.

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