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Ru(II)-Catalyzed C-H Aminocarbonylation of N-(Hetero)aryl-7-azaindoles with Isocyanates. 2018
Taejoo Jeong, and
Suk Hun Lee, and
Rina Chun, and
Sangil Han, and
Sang Hoon Han, and
Yeong Uk Jeon, and
Jihye Park, and
Takehiko Yoshimitsu, and
Neeraj Kumar Mishra, and
In Su Kim
School of Pharmacy , Sungkyunkwan University , Suwon 16419 , Republic of Korea.
The ruthenium(II)-catalyzed C-H aminocarbonylation of N-(hetero)aryl-7-azaindoles with isocyanates is described. The excellent site selectivity at the ortho-position within the N-(hetero)aryl ring was observed to provide ortho-amidated N-(hetero)aryl-7-azaindoles under the mild reaction conditions. The resulting 7-azaindole derivatives can be readily transformed into 7-azaindoles containing carboxylic acid and alkyl amine functional groups.
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